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A container of capacity \( V \) L contains an equilibrium mixture that consists of 2 moles each of \( \mathrm{PCl}_{5}, \mathrm{PCl}_{3} \) and \( \mathrm{Cl}_{2} \) (all as gases). The pressure is \( 30.3975 \mathrm{kPa} \) and temperature is \( T \mathrm{~K} \). A certain amount (' \( x \) ' mole) of \( \mathrm{Cl}_{2}(\mathrm{~g}) \) is now introduced keeping the pressure and temperature constant, until the equilibrium volume becomes \( 2 \mathrm{VL} \). The value of ' \( 90 x \) ' is
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