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Consider the following balanced reactions :
(i) \( \mathrm{K}_{2}\left[\mathrm{PtCl}_{4}\right]+2 \mathrm{NH}_{3} \rightarrow{ }^{\prime} X '+2 \mathrm{KCl} \)
(ii) \( \left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4}\right]\left(\mathrm{NO}_{3}\right)_{2}+2 \mathrm{KCl} \rightarrow{ }^{\prime} \mathrm{Y} '+2 \mathrm{NH}_{3}+2 \mathrm{KNO}_{3} \)
\( P \)
Both \( X \) and \( Y \) have same molecular formula \( \mathrm{Pt} \cdot 2 \mathrm{NH}_{3} \cdot \mathrm{Cl}_{2} \) and \( X \) is more soluble in polar
W solvent such as ehtanol while \( Y \) is soluble in non-polar solvent like petroleum, ether and \( \mathrm{CCl}_{4} \).
Complex \( X \) and \( Y \) are :
(a) ionization isomers
(b) geometrical isomers
(c) solvate isomers
(d) co-ordination isomers
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