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In which of the following the energy change
\( \mathrm{P} \) corresponds to first ionization potential?

W
(1) \( \mathrm{X}_{\mathrm{g}} \rightarrow \mathrm{X}_{(\mathrm{g})}^{+}+\mathrm{e}^{-} \)
(2) \( 2 \mathrm{X}_{\mathrm{g}} \rightarrow 2 \mathrm{X}_{(\mathrm{g})}^{+}+2 \mathrm{e} \)
(3) \( \mathrm{X}_{\mathrm{s}} \rightarrow \mathrm{X}_{(\mathrm{g})}^{+}+\mathrm{e} \)
(4) \( \mathrm{X}_{\mathrm{aq}} \rightarrow \mathrm{X}_{(\mathrm{aq})}^{+}+\mathrm{e} \)
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