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Temperature of maximum density of \( \mathrm{H}_{2} \mathrm{O} \) and \( \mathrm{D}_{2} \mathrm{O} \) is respectively
(a) \( 4{ }^{\circ} \mathrm{C} \) and \( 11.6^{\circ} \mathrm{C} \)
(b) \( 11.6^{\circ} \mathrm{C} \) and \( 4{ }^{\circ} \mathrm{C} \)
(c) \( 4{ }^{\circ} \mathrm{C} \) and \( 12.5^{\circ} \mathrm{C} \)
(d) \( 12.5^{\circ} \mathrm{C} \) and \( 4{ }^{\circ} \mathrm{C} \)
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