Which of the following binary mixtures will have same composition i...

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Which of the following binary mixtures will have same composition in liquid and vapour phase?
\( \mathrm{P} \)
(i) Benzene - Toluene
W
(ii) Water-Nitric acid
(iii) Water-Ethanol
(iv) \( n \)-Hexane - \( n \)-Heptane
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