On the basis of information given below mark the correct option. In...

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On the basis of information given below mark the correct option.
Information : On adding acetone to methanol some of the hydrogen bonds
\( \mathrm{P} \) between methanol molecules break.
(i) At specific composition methanol-acetone mixture will form minimum W boiling azeotrope and will show positive deviation from Raoult's law.
(ii) At specific composition methanol-acetone mixture forms maximum boiling azeotrope and will show positive deviation from Raoult's law.
(iii) At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will show negative deviation from Raoult's law.
(iv) At specific composition methanol-acetone mixture will form maximum boiling azeotrope and will show negative deviation from Raoult's law.
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