Which of the following pairs of gases shows positive P deviation th...

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Which of the following pairs of gases shows positive
P deviation throughout from ideal behaviour?

W
(1) \( \mathrm{N}_{2}, \mathrm{He} \)
(2) \( \mathrm{H}_{2}, \mathrm{He} \)
(3) \( \mathrm{CH}_{4}, \mathrm{He} \)
(4) \( \mathrm{CO}_{2}, \mathrm{H}_{2} \)
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