Consider the following equilibrium in a closed container \( \mathrm{N}_{2} \mathrm{O}_{4}(\mathr....

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Consider the following equilibrium in a closed container \( \mathrm{N}_{2} \mathrm{O}_{4}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}_{2}(\mathrm{~g}) \)
At a fixed temperature, the volume of the reaction container is halved. For this change, which of the following statements hold true regarding the equilibrium constant \( \left(\mathrm{K}_{\mathrm{p}}\right) \) and degree of dissociation \( (\alpha) \) ?
(1) Neither \( K_{p} \) nor \( \alpha \) changes
(2) Both \( K_{p} \) and \( \alpha \) change
(3) \( \mathrm{K}_{\mathrm{p}} \) changes but \( \alpha \) not change
(4) \( \mathrm{K}_{\mathrm{p}} \) not change but \( \alpha \) changes


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