For a reaction, \( A \rightleftharpoons P \), the plots of \( [A] \) and \( [P] \) with time at ...
For a reaction, \( A \rightleftharpoons P \), the plots of \( [A] \) and \( [P] \) with time at temperatures \( T_{1} \) and \( T_{2} \) are given below.
img src=https://penpencil-static-content.s3.ap-south-1.amazonaws.com/5eb393ee95fab7468a79d189/0kvix5b0maixxhxhjmya02bpz.png /
If \( T_{2}>T_{1} \), the correct statement(s) is are
(Assume \( \Delta H^{\ominus} \) and \( \Delta S^{\ominus} \) are independent of temperature and ratio of \( \ln K \) at \( T_{1} \) to \( \ln K \) at \( T_{2} \) is greater than \( T_{2} / T_{1} \). Here \( H, S, G \) and \( K \) are enthalpy, entropy, Gibbs energy and equilibrium constant, respectively.)
(a) \( \Delta H^{\ominus}<0, \Delta S^{\ominus}<0 \)
(b) \( \Delta G^{\ominus}<0, \Delta H^{\ominus}>0 \)
(c) \( \Delta G^{\ominus}<0, \Delta S^{\ominus}<0 \)
(d) \( \Delta G^{\ominus}<0, \Delta S^{\ominus}>0 \)
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