Formation of \( \mathrm{Ni}(\mathrm{CO})_{4} \) and subsequent its decomposition into \( \mathrm...

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Formation of \( \mathrm{Ni}(\mathrm{CO})_{4} \) and subsequent its decomposition into \( \mathrm{Ni} \) and \( \mathrm{CO} \) (recycled) makes
\( \mathrm{P} \)
basis of Monds process
W
\[
\mathrm{Ni}+4 \mathrm{CO} \xrightarrow{\mathrm{T}_{1}} \mathrm{Ni}(\mathrm{CO})_{4} \xrightarrow{\mathrm{T}_{2}} \mathrm{Ni}+4 \mathrm{CO}
\]
\( \mathrm{T}_{1} \) and \( \mathrm{T}_{2} \) are
(1) \( 100^{\circ} \mathrm{C}, 50^{\circ} \mathrm{C} \)
(2) \( 50^{\circ} \mathrm{C}, 100^{\circ} \mathrm{C} \)
(3) \( 57^{\circ} \mathrm{C}, 177^{\circ} \mathrm{C} \)
(4) \( 230^{\circ} \mathrm{C}, 50^{\circ} \mathrm{C} \)
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