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Match the columns
Column-I
Column - II
(A) Number of collisions per
(p) Effective collisions.
second per unit volume of the reaction mixture.
(B) Fraction of molecules
(q) Collision frequency with energies equal to or greater than \( \mathrm{E}_{\mathrm{a}} \)
(C) Molecules for which
(r) \( \mathrm{e}^{-\mathrm{E}_{\mathrm{a}} / \mathrm{RT}} \)
Rate \( =\mathrm{Z}_{\mathrm{AB}} \mathrm{e}^{-\mathrm{E}_{\mathrm{a}} / \mathrm{RT}} \) shows significant deviations
(D) Collision in which molecules
(s) Complex molecules collide with sufficient K.E. and proper orientation.
(a) A-(q), B-(r), C-(s), D-(p)
(b) \( \mathrm{A}- \) (r), \( \mathrm{B}-(\mathrm{q}), \mathrm{C}-(\mathrm{s}), \mathrm{D}-(\mathrm{p}) \)
(c) \( \mathrm{A}- \) (q), B-(s), C-(r), D-(p)
(d) \( \mathrm{A}-(\mathrm{q}), \mathrm{B}-(\mathrm{r}), \mathrm{C}-(\mathrm{p}), \mathrm{D}-(\mathrm{s}) \)
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