\( \mathrm{PCl}_{5} \) and \( \mathrm{PBr}_{5} \) exist in \( s p^{...
\( \mathrm{PCl}_{5} \) and \( \mathrm{PBr}_{5} \) exist in \( s p^{3} d \) hybrid state in gaseous
P phase but in solid state, which of the following
W statement is true?
(1) \( \mathrm{P} \) in \( \mathrm{PCl}_{5} \) exists in \( s p^{3} \)-hybridization state, while \( \mathrm{P} \) in \( \mathrm{PBr}_{5} \) exists in \( s p^{3} d^{2} \) and \( s p^{3}- \) hybridization states
(2) \( \mathrm{P} \) in \( \mathrm{PCl}_{5} \) and \( \mathrm{PBr}_{5} \) exists in \( s p^{3} d^{2} \) and \( s p^{3} \) hybridization state
(3) \( \mathrm{P} \) in \( \mathrm{PCl}_{5} \) exists in \( s p^{3} d^{2} \) and \( s p^{3} \) hybridization states, while \( \mathrm{P} \) in \( \mathrm{PBr}_{5} \) exists in \( \mathrm{sp}^{3} \)-hybridization state
(4) \( \mathrm{P} \) in \( \mathrm{PCl}_{5} \) and \( \mathrm{PBr}_{5} \) exists in \( s p^{3} \)-hybridization state
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