Matrix match \( \left(\mathrm{E}_{\mathrm{Ag}^{+} / \mathrm{Ag}}^{0}=0.8, \mathrm{~K}_{\mathrm{S...
Matrix match \( \left(\mathrm{E}_{\mathrm{Ag}^{+} / \mathrm{Ag}}^{0}=0.8, \mathrm{~K}_{\mathrm{SP}}(\mathrm{AgCl})=10^{-10}\right) \)
\begin{tabular}{|c|l|c|l|}
\hline \multicolumn{2}{|c|}{ Column-I } & \multicolumn{2}{|c|}{ Column-II } \\
\hline & \( \mathrm{Pt} \mid \mathrm{H}_{2}(0.1 \) bar \( ) \mid \) & & \\
A. & \( \begin{array}{l}\mathrm{H}^{+}(0.1 \mathrm{M}) \\
\| \mathrm{H}^{+}(1 \mathrm{M}) \mid \mathrm{H}_{2}(0.01 \\
\text { bar }) \mid \mathrm{Pt}\end{array} \) & p. & \( \begin{array}{l}\text { Concentration } \\
\text { cell }\end{array} \) \\
\hline B. & \( \begin{array}{l}\mathrm{Ag} \mid \mathrm{AgCl}(\mathrm{KCl}, 0.1 \mathrm{M}) \\
\| \mathrm{Ag}^{+}(0.01 \mathrm{M}) \mid \mathrm{Ag}\end{array} \) & q. & \( \mathrm{E}_{\text {cell }}0 \) \\
\hline C. & \( \begin{array}{l}\mathrm{Cu} \mid \mathrm{Cu}^{2+}(0.01 \mathrm{M}) \| \\
\mathrm{Ag}(0.01 \mathrm{M}) \mid \mathrm{Ag}\end{array} \) & \( \mathrm{r} \). & \( \begin{array}{l}\mathrm{E}_{\text {Cell }}^{0}=0 \quad \text { but } \\
\text { cell is working }\end{array} \) \\
\hline & \( \begin{array}{l}\mathrm{Pt} \mid \mathrm{Cl}_{2}(1 \mathrm{bar}) \\
\mathrm{HCl}(0.1 \mathrm{M}) \\
\| \mathrm{NaCl}(0.1 \mathrm{M}) \mid \mathrm{Cl}_{2} \\
(1 \mathrm{bar}) \mid \mathrm{Pt}\end{array} \) & \( \mathrm{s} \). & \( \begin{array}{l}\text { Non-working } \\
\text { cell }\end{array} \) \\
\hline
\end{tabular}
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