State Le Chatliers principle and apply it to the following equilibria: (i) \( 2 \mathrm{NO}(\mat...

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State Le Chatliers principle and apply it to the following equilibria:
(i) \( 2 \mathrm{NO}(\mathrm{g}) \rightleftharpoons \mathrm{N}_{2}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g})+ \) Heat
(ii) \( \mathrm{N}_{2} \mathrm{O}_{4}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}_{2}(\mathrm{~g})- \) Heat
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