A typical characteristic of the representative elements is that the first member of each group g... VIDEO
A typical characteristic of the representative elements is that the first member of each group gives different characteristics as compared to the rest of the members present in that group. Lithium is no exception. Though it is the first member of the alkali metal family (group 1), it is anomalous in behaviour. This may be attributed to the high polarising power, and non-availability of \( d \)-electrons in its valence shell.
The order of solubility of lithium halides in non-polar solvents is:
(A) \( \mathrm{Lil}\mathrm{LiBr}\mathrm{LiCl}\mathrm{LiF} \)
(B) \( \mathrm{LiF}\mathrm{Lil}\mathrm{LiBr}\mathrm{LiCl} \)
(C) \( \mathrm{LiCl}\mathrm{LiF}\mathrm{Lil}\mathrm{LiBr} \)
(D) \( \mathrm{LiBr}\mathrm{LiCl}\mathrm{LiF} \) Lil.
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