Davisson–Germer experiment
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The Davisson–Germer experiment was a 1923-27 experiment by Clinton Davisson and Lester Germer at Western Electric (later Bell Labs), in which electrons, scattered by the surface of a crystal of nickel metal, displayed a diffraction pattern. This confirmed the hypothesis, advanced by Louis de Broglie in 1924, of wave-particle duality, and also the wave mechanics approach of the Schrödinger equation. It was an experimental milestone in the creation of quantum mechanics.
Source: https://en.wikipedia.org/wiki/Davisson–Germer_experiment
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