Resident Evil 5 - Professional S-Rank - Chapter 1-1
For this mode, I decided to split the chapters individually instead of grouping them like the previous difficulties. One wrong move on Professional can likely cost you the rank and there most likely will be times when you will have to restart, whether due to poor AI on Sheva's part, or just bad luck.
In Professional, in order to obtain S-Rank, I would highly recommend the infinite Lightning Hawk magnum due to it's quick firing speed, along with an infinite Rocket Launcher as both items will one-shot most, if not all bosses and enemies. Second, I would carry as many healing items as possible, for even though you might be fine, Sheva's AI can sometimes cost you an entire run in that chapter.
Once you have all that, you should be ready to start the Professional run for S-Rank. Again, it's not necessary, but highly recommended that infinite ammo is unlocked for the two weapons listed above, as it will make the difficulty much easier. This run was done with an AI in all chapters, as I'm assuming that's how most people are playing the game.
Thanks and good luck on the run!
For this first chapter, I would recommend staying near the exit of the level once the you are able to get past the first green gate. Blowing up the nearby stands will help open up the level, allowing you to easily see where the enemies are so that you're never blindsided. Stick by the exit with several healing items and you should be good to go.
And that's the end of Chapter 1-1.
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