Spectroscopy: Principle and applications in structure elucidation: (i) Rotational—Diatomic molecules

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Diatomic (2024)
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Spectroscopy:
Principle and applications in structure elucidation:
(i) Rotational—Diatomic molecules; isotopic substitution and rotational constants.
(ii) Vibrational—Diatomic molecules, linear triatomic molecules, specific frequencies of functional groups in
polyatomic molecules.
(iii) Electronic—Singlet and triplet states. n and transitions; application to conjugated double bonds and conjugated
carbonyls Woodward-Fieser rules; Charge transfer spectra.
(iv) Nuclear Magnetic Resonance (1
HNMR): Basic principle; chemical shift and spin-spin interaction and coupling
constants.
(iv) Mass Spectrometry: —Parent peak, base peak, metastable peak, McLafferty rearrangement



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