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The first order rate constant \( \mathrm{k} \) is related to temperature as \( \log \mathrm{k}=15.0-\left(10^{6} / \mathrm{T}\right) \). Which of the following pair of
\( \mathrm{P} \) value is correct?

W
(1) \( \mathrm{A}=10^{15} \) and \( \mathrm{E}=1.9 \times 10^{4} \mathrm{KJ} \)
(2) \( A=10^{-15} \) and \( \mathrm{E}=40 \mathrm{KJ} \)
(3) \( \mathrm{A}=10^{15} \) and \( \mathrm{E}=40 \mathrm{KJ} \)
(4) \( \mathrm{A}=10^{-15} \) and \( \mathrm{E}=1.9 \times 10^{4} \mathrm{KJ} \)
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