What is decreasing order of basicity of \( 1^{\circ}, 2^{\circ} \) and \( 3^{\circ} \) ethyl ami...

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What is decreasing order of basicity of \( 1^{\circ}, 2^{\circ} \) and \( 3^{\circ} \) ethyl amines and ammonia in aqueous medium?
1. \( \mathrm{NH}_{3}\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{3} \mathrm{~N} \)
2. \( \left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{3} \mathrm{~N}\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}\mathrm{NH}_{3} \)
3. \( \left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{3} \mathrm{NH}\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{3} \mathrm{~N}\mathrm{NH}_{3} \)
4. \( \left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{3} \mathrm{~N}\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}\mathrm{NH}_{3} \)
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