Which of the following is known to exist?....

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Which of the following is known to exist?
(1) \( \mathrm{VBr}_{5} \)
(2) \( \mathrm{VI}_{4} \)
(3) \( \mathrm{VF}_{4} \)
(4) \( \mathrm{TiBr}_{2} \)
\( \mathrm{P} \)
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