Which one the following reaction is not associated with the Solvay ...

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Which one the following reaction is not associated with the Solvay process ?
(a) \( \mathrm{NH}_{3}+\mathrm{H}_{2} \mathrm{O}+\mathrm{CO}_{2} \) (excess) \( \longrightarrow \mathrm{NH}_{4} \mathrm{HCO}_{3} \)
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(b) \( \mathrm{NaCl}+\mathrm{NH}_{4} \mathrm{HCO}_{3} \longrightarrow \mathrm{NaHCO}_{3}+\mathrm{NH}_{4} \mathrm{Cl} \)
W
(c) \( 2 \mathrm{NaHCO}_{3} \stackrel{\Delta}{\longrightarrow} \mathrm{Na}_{2} \mathrm{CO}_{3}+\mathrm{H}_{2} \mathrm{O}+\mathrm{CO}_{2} \)
(d) \( 2 \mathrm{NaOH}+\mathrm{CO}_{2} \longrightarrow \mathrm{Na}_{2} \mathrm{CO}_{3}+\mathrm{H}_{2} \mathrm{O} \)
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