Which will form maximum boiling azeotrope?....

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Which will form maximum boiling azeotrope?
\( \mathrm{P} \)
(1) \( \mathrm{C}_{6} \mathrm{H}_{6}+\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CH}_{3} \) solution
W
(2) \( \mathrm{HNO}_{3}+\mathrm{H}_{2} \mathrm{O} \) solution
(3) \( \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}+\mathrm{H}_{2} \mathrm{O} \) solution
(4) n-hexane and n-heptane


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