\[ \begin{array}{ll} \mathrm{C}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{~g}) \longrightarrow \mathrm{...

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\[
\begin{array}{ll}
\mathrm{C}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{~g}) \longrightarrow \mathrm{CO}_{2},(\mathrm{~g}) ; \Delta \mathrm{H}=-94.3 \mathrm{kcal} / \mathrm{mol} \\
\mathrm{CO}(\mathrm{g})+\frac{1}{2} \mathrm{O}_{2}(\mathrm{~g}) \longrightarrow \mathrm{CO}_{2}(\mathrm{~g}) ; & \Delta \mathrm{H}=-67.4 \mathrm{kcal} / \mathrm{mol} \\
\mathrm{O}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{O}(\mathrm{g}) ; & \Delta \mathrm{H}=117.4 \mathrm{kcal} / \mathrm{mol} \\
\mathrm{CO}(\mathrm{g}) \longrightarrow \mathrm{C}(\mathrm{g})+\mathrm{O}(\mathrm{g}) ; & \Delta \mathrm{H}=230.6 \mathrm{kcal} / \mathrm{mol}
\end{array}
\]
- Calculate \( \Delta \mathrm{H} \) for \( \mathrm{C}(\mathrm{s}) \longrightarrow \mathrm{C}(\mathrm{g}) \) in \( \mathrm{kcal} / \mathrm{mol} \).
- (a) 171
(b) 154
- (c) 117
(d) 145
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