Determine which of the following reactions at constant pressure represent surrounding that do wo...

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Determine which of the following reactions at constant pressure represent surrounding that do work on the system?
I. \( 4 \mathrm{NH}_{3}(\mathrm{~g})+7 \mathrm{O}_{2}(\mathrm{~g}) \longrightarrow 4 \mathrm{NO}_{2}(\mathrm{~g})+6 \mathrm{H}_{2} \mathrm{O}(\mathrm{g}) \)
II. \( \mathrm{CO}(\mathrm{g})+2 \mathrm{H}_{2}(\mathrm{~g}) \longrightarrow \mathrm{CH}_{3} \mathrm{OH}(\ell) \)
III. \( \mathrm{C}(\mathrm{s} \), graphite \( )+\mathrm{H}_{2} \mathrm{O}(\mathrm{g}) \longrightarrow \mathrm{CO}(\mathrm{g})+\mathrm{H}_{2}(\mathrm{~g}) \)
IV. \( \mathrm{H}_{2} \mathrm{O}(\mathrm{s}) \longrightarrow \mathrm{H}_{2} \mathrm{O}(\ell) \)
(a) III, IV
(b) II and III
- (c) II, IV
(d) I and II, IV
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