In case of nitrogen \( \mathrm{NCl}_{3} \) is possible but not \( \...

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In case of nitrogen \( \mathrm{NCl}_{3} \) is possible but not \( \mathrm{NCl}_{5} \) while in case of phosphorous, \( \mathrm{PCl}_{3} \) as well as \( \mathrm{PCl}_{5} \) are possible. This is due to :-
(1) Availability of vacant d-orbitals in \( \mathrm{P} \) butnot in \( \mathrm{N} \)
\( \mathrm{P} \)
(2) Lower electronegativity of \( \mathrm{P} \) than \( \mathrm{N} \)
W
(3) Lower tendency of \( \mathrm{H} \)-bond formation in \( \mathrm{P} \) than \( \mathrm{N} \)
(4) Occurence of \( \mathrm{P} \) in solid while \( \mathrm{N} \) in gaseous state at room temperature
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