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In solid state \( \mathrm{PCl}_{5} \) exits as
(1) \( \mathrm{PCl}_{4}{ }^{-} \& \mathrm{PCl}_{6}^{+} \)
\( \mathrm{P} \)
(2) \( \mathrm{PCl}_{4}^{+} \& \mathrm{PCl}_{6}^{-} \)
W
(3) \( \mathrm{PCl}_{3}{ }^{-} \& \mathrm{PCl}_{5}{ }^{+} \)
(4) \( \mathrm{PCl}_{6}^{+} \& \mathrm{PCl}_{4}^{+} \)
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