\( \mathrm{PCl}_{5} \) exists but \( \mathrm{NCl}_{5} \) does not b...

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\( \mathrm{PCl}_{5} \) exists but \( \mathrm{NCl}_{5} \) does not because
P
(1) Nitrogen has no vacant 2d-orbitals
W
(2) \( \mathrm{NCl}_{5} \) is unstable
(3) Nitrogen atom is much smaller than \( \mathrm{P} \)
(4) Nitrogen is highly inert
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