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The units I used for this battle are Dorothy, Viper (w/Maxed Favorite Treasure), Ludmilla: Winter Owner, Crown and Privaty. The team's Skill levels and equipment are shown before the fight begins in this video. I recommend using team for survivability, high damage output, and the fact that this boss is weak against Water. You can also either swap out Viper, and Crown for Grave and Red Hood or use Volume, Crown, Quency: Escape Queen, Ludmilla: Winter Owner, and Phantom as a team to see which result works out better for you at Mock Battle. Be sure to quickly take out both left and right Large Caliber Rifle parts when the fight starts and you must use a Water unit whenever Black Smith does its two QTE attacks since it will surround itself with a Fire Shield. Best of luck to you and thanks for watching.
To find out which units are in the meta, I recommend checking out this tier list so that you know who to focus on when it comes to skill building priorities:
https://www.prydwen.gg/nikke/tier-list/
To know which skill and bursts are prioritize in leveling, check this link out:
https://nikke.gg/skill-priority-guide/
To find out how to properly Overload your units' gear, check out this link:
https://nikke.gg/overload-gear-priority/