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When Moe's "evening rush" comes into the bar one night, he tells his customers that they are responsible for 91% of all traffic accidents in Springfield so they will now have to choose designated drivers to prevent any more accidents. This prompts Moe to hold a pickled egg drawing to see who will stay sober and be the designated driver. Barney, the most unlikely one, draws the black egg and therefore becomes the designated driver for the night.

While his friends enjoy their drunken antics, Barney is twitching uncontrollably and is not even sure if he can tolerate having to be sober period much less around everyone else getting drunk.

This is from Season 9 Episode 1's The City of New York vs. Homer Simpson.