Game:

Pokémon Stadium (1999)

Duration: 36:05

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Here is the Master Ball difficulty for Prime Cup, and in this one, the Trainers are more difficult than the last few difficulty levels for Prime Cup. All Trainers use Level 100 Pokémon, and for the team that I selected, I chose Kadabra and Jynx for Psychic-types, Electrode and Zapdos for Electric-types, Electrode has Thunder Wave to help against some opponents. Rhydon was picked because of Earthquake and its type helps against some opponents, and I chose Vaporeon for the Water-type.
I will list each Trainers, and the nicknames of the Pokémon, with the species name of the Pokémon in brackets.
Battle 1: Cueball
pinsir (Pinsir): Strength, Swords Dance, Bind, Seismic Toss
beedrill (Beedrill): Twineedle, Focus Energy, Pin Missile, Hyper Beam
flareon (Flareon): Flamethrower, Sand-Attack, Double-Edge, Quick Attack
magmar (Magmar): Fire Punch, Confuse Ray, Mega Punch, Metronome
raticate (Raticate): Hyper Fang, Super Fang, Dig, Quick Attack
kangaskhan (Kangaskhan): Dizzy Punch, Rock Slide, Earthquake, Substitute

Battle 2: Rocket
Jynact1 (Jynx): Ice Punch, Lovely Kiss, Thrash, Body Slam
Golemact2 (Golem): Earthquake, Mega Kick, Rock Slide, Bide
Golbact3 (Golbat): Bite, Confuse Ray, Mega Drain, Toxic
Aerodact4 (Aerodactyl): Sky Attack, Supersonic, Fly, Hyper Beam
Peract5 (Persian): Slash, Pay Day, Screech, Hyper Beam
Victract6 (Victreebel): Razor Leaf, Stun Spore, Mega Drain, Growth

Battle 3: Judoboy
Champ (Machamp): Submission, Focus Energy, Dig, Fire Blast
Scy (Scyther): Wing Attack, Focus Energy, Take Down, Swift
Hitlee (Hitmonlee): Hi Jump Kick, Focus Energy, Mega Kick, Swift
Prime (Primeape): Submission, Focus Energy, Rock Slide, Thrash
Nido (Nidoking): Earthquake, Focus Energy, Thunder, Surf
Jolt (Jolteon): Thunderbolt, Focus Energy, Double Kick, Take Down

Battle 4: Gambler
Urosta (Tauros): Horn Drill, Body Slam, Fissure, Take Down
Broslow (Slowbro): Fissure, BubbleBeam, Thunder Wave
Triodug (Dugtrio): Fissure, Rock Slide, Body Slam
Oiseblast (Blastoise): Fissure, Body Slam, BubbleBeam
Bokar (Arbok): Fissure, Glare, Bite, Mega Drain
Nitedrago (Dragonite): Horn Drill, Agility, BubbleBeam, Thunder Wave

Battle 5: Cool♀
Starmance (Starmie): Surf, Thunder, Psychic, Recover
Dewgance (Dewgong): Ice Beam, Headbutt, Surf, Toxic
Omastance (Omastar): Hydro Pump, Withdraw, Spike Cannon, Hyper Beam
Polwrance (Poliwrath): Hydro Pump, Hypnosis, Submission, Amnesia
Venance (Venusaur): Razor Leaf, Leech Seed, Toxic, Growth
Eggustance (Exeggutor): SolarBeam, Leech Seed, Egg Bomb, Toxic

Battle 6: Birdboy
Articash (Articuno): Ice Beam, Agility, Fly, Mist
Moltrash (Moltres): Fire Blast, Agility, Sky Attack, Take Down
Zapdash (Zapdos): Thunder, Agility, Drill Peck, Thunder Wave
Charizash (Charizard): Fire Blast, Slash, Earthquake, Fire Spin
Pidgeotash (Pidgeot): Fly, Mirror Move, Toxic, Hyper Beam
Fearash (Fearow): Drill Peck, Agility, Swift, Fly

Battle 7: Lab Man
Kazam-Ala (Alakazam): Psychic, Recover, Seismic Toss, Disable
To-Dit (Ditto): Transform
Gan-Gen (Gengar): Dream Eater, Hypnosis, Night Shade, Confuse Ray
Pidash-Ra (Rapidash): Fire Spin, Toxic, Stomp, Agility
Pras-La (Lapras): Hydro Pump, Sing, Ice Beam, Confuse Ray
Chu-Rai (Raichu): Thunderbolt, Double Team, Thunder Wave, Flash

Battle 8: Cool♂
Mewstor (Mew): Psychic, Thunder Wave, Tri Attack, Flash
Rodestor (Electrode): Thunderbolt, Flash, Thunder Wave, Hyper Beam
Snorestor (Snorlax): Double-Edge, Reflect, Thunder, Rest
Cloystor (Cloyster): Ice Beam, Take Down, Surf, Toxic
Donstor (Rhydon): Earthquake, Body Slam, Rock Slide, Thunderbolt
Caninestor (Arcanine): Fire Blast, Agility, Dig, Hyper Beam

The Trainer take it a step up in difficulty, but the first three battles shouldn't be very hard if you have some good counters to them, but there are some moves to watch out for. Gambler uses the Horn Drill and Fissure strategy with moves that lower Speed, Birdboy uses all three of the Legendary Birds, Lab Man does prove to be a challenge, some of his Pokémon can inflict status conditions, and the real challenge is against Cool♂, he has Mew on his team, and he uses some of the most powerful Pokémon, like Snorlax, Rhydon, and Arcanine, and he has Electrode which can inflict paralysis with Thunder Wave. He does use that Mew everytime, and this can be a tricky opponent to take down because Mew has base 100 in every stat, and Psychic is one of the most overpowered types in the game, you can bring a Thunder Wave user to paralyze Mew, and have some Pokémon that can take on the rest of his team.
After completing the Master Ball difficulty in Prime Cup, all of the Pokémon that you used will be registered to the Hall of Fame, and you unlock Doduo GB Tower for completing the Master Ball difficulty on whichever cup you did first, this allows you to play the game at twice the speed, I don't know if ever they will add Pokémon Red, Blue, and Yellow to Game Boy - Nintendo Switch Online and if Pokémon Stadium will connect with those games.

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